Total Synthesis of Putative 11-epi-Lyngbouilloside Aglycon
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چکیده
منابع مشابه
Total Synthesis of Putative 11-epi-Lyngbouilloside Aglycon
We report here the total synthesis of 11-epi-lyngbouilloside aglycon. Our strategy features a Boeckman-type esterification followed by a RCM to form the 14-membered ring macrolactone and a late-stage side chain introduction via a Wittig olefination. Overall, the final product was obtained in 20 steps and 2% overall yield starting from commercially available 3-methyl-but-3-enol. Most importantly...
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ژورنال
عنوان ژورنال: Frontiers in Chemistry
سال: 2016
ISSN: 2296-2646
DOI: 10.3389/fchem.2016.00034